ELECTROCHEMICAL FABRICATION OF TWO TERMINAL NANOSCALE RESISTIVE SWITCHES

Department

Chemistry

Abstract

Here we report a simple electrochemical approach for fabricating two terminal resistive switching devices. This involved electrodeposition of silver (Ag) onto one set of electrodes (E1) that connected to a second set of electrodes (E2) of an interdigitated array of electrodes with a 5µm separation. Under appropriate deposition conditions, Ag nanowires (Ag NWs) grew from E2 and cross over to E1. Then Ag was removed from electrodes E2 by electrochemical oxidation, leading to a break in the connection between Ag NW and E2. The initially high resistance (Off state) decreased dramatically (On state) at potentials greater than ± 1 V due to Ag filament formation between the Ag NW and E2 electrode. These filament based switching devices exhibited an on/off ratio over 104 and long endurance.

Presentation format

Poster

Poster Number

123

This document is currently not available here.

Share

COinS
 

ELECTROCHEMICAL FABRICATION OF TWO TERMINAL NANOSCALE RESISTIVE SWITCHES

Here we report a simple electrochemical approach for fabricating two terminal resistive switching devices. This involved electrodeposition of silver (Ag) onto one set of electrodes (E1) that connected to a second set of electrodes (E2) of an interdigitated array of electrodes with a 5µm separation. Under appropriate deposition conditions, Ag nanowires (Ag NWs) grew from E2 and cross over to E1. Then Ag was removed from electrodes E2 by electrochemical oxidation, leading to a break in the connection between Ag NW and E2. The initially high resistance (Off state) decreased dramatically (On state) at potentials greater than ± 1 V due to Ag filament formation between the Ag NW and E2 electrode. These filament based switching devices exhibited an on/off ratio over 104 and long endurance.